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Nice characters!
Yes, that's why I asked for a program which is NOT for pixel art, maybe my answer was not clear enough in the beginning ^^
I actually got quite into Krita already and think I will stick with it.
With "vector" look I only meant something NOT pixel-looking, so more or less smooth looking.
https://i.imgur.com/4ZBkYIQ.jpg
https://i.imgur.com/X6u3K1y.png (not finished)
I made 2 concepts for characters in Krita, 1 is still in work though. If I keep improving, I might start with game assets maybe soon <img src="{SMILIES_PATH}/icon_e_smile.gif" alt=":)" title="Smile">