Firstly, you need to square 64, so 64 x 64 = 4096
So why does Construct think the density is 81? 81 is the square of 9, so I'm guessing Construct thinks the box is 9 x 9 for some reason - maybe it's resized in the layout?
I'm curious too so am about to experiment, but if you can also upload the project, that might help.
EDIT - I just recreated your steps and mine's reporting a mass of 81.9199979305! No idea why! I'll keep experimenting...
EDIT 2 - added a sprite with size = 64 x 64 (instead of 1 x 1) and get the same mass...