Probably, most likely no. Unless you are prepared to nuke your bank account. You can buy pictures here for some nice sums:
gettyimages.at/fotos/messi-posed
Which have additional restrictions applied in how you can use them. As in, not commercially (e.g. don't plan on making money) etc. Unless you get specific permission (seems like you can do that on getty images) which, I'd assume, costs ungodly amounts of cash.
You could, maybe, meet Messi personally, snap a picture and ask him directly if you can use it in your game. Good luck :)