First, if you haven't done this yet, you need to load the array json file into the Items array object using AJAX. See the first two events in this template for an example: editor.construct.net
Custom column and row names in the Array Editor are just for your convenience, you can't use these names to access data. So you will need to use numbers for x and y index - Items.at(0,4)
If your table is big it will be difficult to remember what all those row numbers mean. You can create a bunch of constant variables and use them to make your code more readable:
ITEMNAME_ROW=1
HEALTH_ROW=2
ARMOR_ROW=3
EQUIP_ROW=4
INSPECT_ROW=5
Set Description to Item.at(0, INSPECT_ROW)