What format are your videos in? Are you supporting more than one codec?
It appears from THIS article that whilst most browsers support the MP4 H.264 codec, chromium - which NW.js uses - does not.
[quote:2tc7a8ed]The MP4 container format with the H.264 video codec and the AAC audio codec is natively supported by desktop/mobile Internet Explorer, Safari and Chrome, but Chromium and Opera do not support the format.
After a quick test, I verified that NW.js after export plays webm and ogg but not MP4 H.264.